Preheat your oven to 350°F (175°C). Grease two 8-inch round cake pans, line the bottoms with parchment paper, and dust the sides lightly with flour. Tap out any excess flour and set the pans aside. In a large bowl, whisk together the all-purpose flour, cocoa powder, granulated sugar, brown sugar, baking soda, baking powder, and salt until well combined. Add the vegetable oil, sour cream, eggs, and vanilla extract to the dry ingredients, and whisk until the batter is smooth and free of streaks. It will be quite thick at this point. In a separate cup, dissolve the instant espresso powder into 1 cup of boiling water. Pour this hot espresso mixture into the cake batter and whisk until everything is well incorporated and smooth. Divide the batter evenly between the two prepared pans. Bake on the center rack of your preheated oven for 35 to 40 minutes, or until a skewer inserted into the center comes out with a few moist crumbs attached. Allow the cakes to cool in their pans for about 10 minutes. Then place a piece of parchment paper on top of each cake and invert them onto a wire cooling rack—this helps prevent sticking, as the cakes are very moist. Let the cakes cool completely to room temperature before assembling.