Preheat your oven to 350°F (175°C). Line a 12-cup muffin pan with cupcake liners and set aside.
In a large mixing bowl, pour ¾ cup of warm water, then stir in 1 teaspoon of instant coffee or espresso powder until fully dissolved.
Add ⅓ cup of melted chocolate chips and ⅓ cup of sifted unsweetened cocoa powder. Whisk until the mixture is smooth and well combined.
Next, whisk in 2 large eggs, ⅓ cup of vegetable or canola oil, 1 teaspoon of vanilla extract (or vanilla bean paste), and 1 teaspoon of white vinegar.
Sift the dry ingredients—¾ cup all-purpose flour, ¾ cup granulated sugar, ½ teaspoon baking soda, and ½ teaspoon fine salt—directly into the bowl. Gently whisk until the batter is smooth and just combined. It will be thin—this is normal.
Divide the batter evenly among the cupcake liners, filling each about ⅔ full.
Bake for 17–19 minutes, or until a toothpick inserted into the center comes out with a few moist crumbs.
Remove from the oven and let the cupcakes cool in the pan for 10 minutes, then transfer them to a wire rack to cool completely.
Quick tip: To speed up the cooling process, place the pan in the freezer for 15 minutes after the initial 10-minute cooling period.